Saravanan, KR. and Sathyamoorthi, S. and Velayutham, D. and Suryanarayanan, V. (2013) Electrodeposition of nickel on boron-doped diamond from an air-stable methyl sulphate anion based ionic liquid. Electrochimica Acta, 98. pp. 88-93. ISSN 0013-4686
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Abstract
Electrodeposition of nickel had been successfully carried out for the first time in the ionic liquid triethylmethylammonium methyl sulphate (TEMAMS) on boron-doped diamond (BDD) along with glassy carbon electrode (GC). The electrochemical reduction of Ni (II) ions takes place slightly at a more positive potential on the BDD than the GC in this medium. The nickel deposition proceeds via three-dimensional instantaneous nucleation on the BDD and progressive on the GC. Surface morphologic characteristics of Ni deposits obtained on the BDD and GC at different deposition potentials were characterised by SEM and AFM
Item Type: | Article |
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Uncontrolled Keywords: | Methyl sulphate anion; Ionic liquids; Boron-doped diamond; Glassy carbon; Cyclic voltammetry |
Subjects: | Electrodeposition Electroorganic |
Divisions: | UNSPECIFIED |
Depositing User: | Dr. N Meyyappan |
Date Deposited: | 30 May 2013 06:40 |
Last Modified: | 30 May 2013 06:40 |
URI: | http://cecri.csircentral.net/id/eprint/3027 |
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