Varadharaj, A. and Prabhakararao, G. (1990) Anodic current peaks during cathodic sweep in cyclic voltammetric studies on gallium film electrode in alkaline solutions. Bulletin of Electrochemistry, 06 (04). pp. 482-483. ISSN 0256-1654

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Abstract

A gallium film electrode (prepared ‘in situ’) yielded reliable and reproducible polarisation data, indicating its potentialities in kinetic studies. The cyclic voltammogram indicates the appearance of anodic peak during the cathodic sweep and has been noted in this work. The potential regime over which the anodic peak currents appeared, the effect of alkali concentration sweep rate and the reversal of voltage excursion at different potential regimes on the anodic peak current have been investigated. The resultant experimental observations indicate the formation of a lower valent intermediate to be responsible for yielding this anodic peak current

Item Type: Article
Uncontrolled Keywords: Cyclic voltammetry; Gallium film electrode; Secondary anodic peak
Subjects: Electrohydrometallurgy
Divisions: UNSPECIFIED
Depositing User: ttbdu cecri
Date Deposited: 21 May 2012 11:58
Last Modified: 21 May 2012 11:58
URI: http://cecri.csircentral.net/id/eprint/2683

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