Ramachandran, P. and Venkateswaran, K.V. and Srinivasan, R.
(1986)
Catalytic anodes in electrowinning - inhibition of poisoning :part I. Cyclic voltammetric studies.
Bulletin of Electrochemistry , 2 (6).
pp. 639-641.
ISSN 0256-1654
Abstract
Poisoning of the catalytic anodes of Mn2+ ion in metal winning electrolytes has been investigated.
Addition of soluble phosphorous (V) and arsenic (Ill) compounds has been examined as
a deterrent for MnOz deposition using cyclic voltamrnetric technique. Probable role of these compounds
in the inhibition of anodic formution of MnOz is discussed. Platinum, RuOz film electrode and
Ru02 powder compact electrode have been studied in this context.
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