Nathirabegum, S. and Vasudevarao, P.V. (1985) Kinetics of dissolution of zinc in zinc chloride solution. Bulletin of Electrochemistry , 01 (05). pp. 447-449. ISSN 0256-1654

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Abstract

The kinetics of dissolution of zinc in acidic zinc chloride solution have been investigated in order to understand and optimize its performance in zinc-chlorine hydrate battery. Polarisation experiments were carried out using pure zinc rods and electrodeposited zinc as electrods. For a concentration change of zinc chloride from 0.5 to 1.5 M. the exchange current densities were found to vary from 1.4 to 2.4 mA/cm2 in the case of cast zinc rod electrodes, and from 2.2 to 6.2 mA/cm2 in the case of electrodepasited zinc; this increase is attributed to the greater reactivity as well as the increased surface area of the freshly electrodeposited zinc

Item Type: Article
Uncontrolled Keywords: Kinetics; Zinc-chlorine battery; Dissolution of zinc
Subjects: Electrochemical Power Sources
Divisions: UNSPECIFIED
Depositing User: ttbdu cecri
Date Deposited: 20 Mar 2012 18:09
Last Modified: 20 Mar 2012 18:09
URI: http://cecri.csircentral.net/id/eprint/2132

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