Kalaiselvi, N. and Thirunakaran, R. and Periasamy, P. and Sakthivel, M. and Muniyandi, N. (2005) LiMgy1Cry2Mn2-y1-y2O4 (0.0 < 0.30; Y2=0.30-Y1) as a cathode active material for lithium batteries. Portugaliae Electrochimica Acta, 23 (2). pp. 247-262.

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Abstract

LiMn2O4 is an attractive 4 V positive material in lithium rechargeable batteries owing to its favourbale electrochemical characteristics besides its economic and environmental advantages. However, problems of limited cyclability, especiallyat elevated temperatures, have limited the uitlity and commercialization of this cathdoe material. Stabilization of the LiMn2O4 spinel structure has been sought to be ralzied by doping the spinel with suitable cations. In this paper, the results of an exploratory research on the cpacity and cyclability of LiMn2o4 cathodes simultaneously doped with Cr3+ and Mg2+ arereported.

Item Type: Article
Uncontrolled Keywords: magnesium; chromium; LiMn2O4; cyclic voltammetry; impedance measurements; lithium battery cathode
Subjects: Lithium batteries
Electrochemical Power Sources
Divisions: UNSPECIFIED
Depositing User: TTBD CECRI
Date Deposited: 17 Jan 2012 06:11
Last Modified: 17 Jan 2012 06:11
URI: http://cecri.csircentral.net/id/eprint/154

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