Prakash, T.P. and Trivedi, D.C.
(1988)
Electrochemical modification of electrode by O-phenelynediamine.
Bulletin of Electrochemistry , 04 (06).
pp. 587-592.
ISSN 0256-1654
Abstract
The surface changes occur when either a platinum or stainless steel electrode is polarised in acetonitrile containing LiC104 or NaC104 and o-phenylenediamine (OPD). While an adherent yellowish brown film formation takes place on anode surface white porous, inhomogeneous deposit is found on the cathode. In this investigation it has been established that the anodically polymerised film can be used as chemically modified electrode for the oxidation of phenol and aniline. It has also been observed that for the formation of cathodic deposit, water in the electrolyte is a must. The products have been identified by I.R. spectra
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