Nathirabegum, S. and Vasudevarao, P.V.
(1985)
Kinetics of dissolution of zinc in zinc chloride solution.
Bulletin of Electrochemistry , 01 (05).
pp. 447-449.
ISSN 0256-1654
Abstract
The kinetics of dissolution of zinc in acidic zinc chloride solution have been investigated in order to
understand and optimize its performance in zinc-chlorine hydrate battery. Polarisation experiments were
carried out using pure zinc rods and electrodeposited zinc as electrods. For a concentration change of
zinc chloride from 0.5 to 1.5 M. the exchange current densities were found to vary from 1.4 to 2.4 mA/cm2 in
the case of cast zinc rod electrodes, and from 2.2 to 6.2 mA/cm2 in the case of electrodepasited zinc; this
increase is attributed to the greater reactivity as well as the increased surface area of the freshly
electrodeposited zinc
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