Trivedi, D.C. (1986) Electro oxidation under phase transfer condition. Bulletin of Electrochemistry , 2 (3). pp. 285-287. ISSN 0256-1654

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Abstract

A new redox phaselransfer catalyst is reported, which in its oxidised form is soluble is non-polar organic phase and in the reduced form is soluble in aqueous phase. The reduced form gets oxidised at anode surface and gets transferred to non-aqueous medium,.where this brings about the oxidation of organic substrate, which is otherwise not possible due to factors like nonsolubility in aqueous phase, steric hindrance etc. By this technique 1,7,7 trimethyl bicyclo heptane-2-1 (Isoborneol) and 2.2 dimethyl 3- methylene bicyclo (2,2,1) heptane (camphene) have been selectively 'oxidised.

Item Type:	Article
Uncontrolled Keywords:	Phase transfer catalysis; Steric hindrance; camphor
Subjects:	Electrochemical Materials Science
Divisions:	UNSPECIFIED
Depositing User:	ttbdar CECRI
Date Deposited:	23 Mar 2012 12:55
Last Modified:	23 Mar 2012 12:55
URI:	http://cecri.csircentral.net/id/eprint/2201

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