Parvathi, N. and Sulochana, N. and Muralidharan, V.S.
(2004)
Cyclic voltammetric reduction of 7-hydroxy and acetoxy flavones at glassy carbon electrode.
Bulletin of Electrochemistry , 20 (2).
pp. 93-96.
ISSN 0256-1654
Abstract
Elecrrochemtcal reduction behavior of 7-acetoxyJlavone was compared .with 7-hydroxyfavone on glassy
carbon electrode with DMF and 60% DMF/Britton Robinson bufler at pH 3.8 & 10.1 using cyclic
voltammetty. Single irreversible reduction waves were observed due to the reduction of keto moiety. The
eflects of change in medium, pH and sweep rate were evaluated The electrode process was found to be
d~flusion controlled and enhanced substituent eflect was noticed due to extended conjugation. Kinetic
parameters were calculated fram cyclic voltammetric measurements using R.S.Nicholson and IShain's
equation.
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