Song, C.H. and Stephan, A.M. and Jeong, S.K. and Hwang, Y.J. and Kim, A.R. and Nahm, K.S. (2006) Influence of Solvents on the Structural and Electrochemical Properties of Li†Li0.2Ni0.1Co0.2Mn0.5‡O2 Prepared by a Solvothermal Reaction Method. Journal of the Electrochemical Society, 153 (2). A390-A395. ISSN 0013-4651

PDF - Published Version Restricted to Registered users only Download (288Kb) | Request a copy

Abstract

Solid solutions of LiLi0.2Ni0.1Co0.2Mn0.5O2 were prepared by solvothermal reaction with three different solvents, namely, methanol, ethanol, and 1-propanol. The prepared compounds were subjected to X-ray diffraction XRD, Raman, Fourier transform infrared, and charge–discharge studies. XRD studies revealed that the prepared compounds are of layered structure with space group R3¯m. The sample which was prepared using 1-propanol as solvent delivered the highest discharge capacity of 205 mAh/g. The electrochemical and structural properties of the prepared compounds are influenced by the physical properties of the solvents.

Item Type:	Article
Subjects:	Electrochemical Power Sources
Divisions:	UNSPECIFIED
Depositing User:	ttbdu cecri
Date Deposited:	25 Jan 2012 12:28
Last Modified:	25 Jan 2012 12:28
URI:	http://cecri.csircentral.net/id/eprint/736

Actions (login required)

View Item