Hwang, Y.J. and Nahm, K.S. and Premkumar, T. and Manuelstephan, A. (2008) Poly(vinylidene fluoride-hexafluoropropylene)-based membranes for lithium batteries. Journal of Membrane Science, 310 (1-2). pp. 349-355. ISSN 0376-7388

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Abstract

Poly(vinylidene fluoride-hexafluoropropylene) (PVdF-HFP) copolymer membranes were prepared by a phase inversion technique with poly(ethylene glycol) as an additive and tetrahydrofuran or acetone or dimethylformamide as solvent. The morphology, ionic conductivity and uptake of electrolyte solution by the polymer membranes were studied. The amount of intake of electrolyte solution by the polymer membranes increases with the increase of PEG content. The morphology and ionic conductivity of the polymer membranes (PM) are correlated with the physical properties of the solvents used in the phase inversion process. The cycling behavior of the membrane was examined with Li/LiCoO2 cells.

Item Type: Article
Uncontrolled Keywords: Polymer electrolyte membranes; Phase inversion method; Lithium batteries; Ionic conductivity; Charge–discharge studies
Subjects: Lithium batteries
Electrochemical Power Sources
Divisions: UNSPECIFIED
Depositing User: ttbdu cecri
Date Deposited: 31 Mar 2012 11:16
Last Modified: 15 Jun 2012 09:23
URI: http://cecri.csircentral.net/id/eprint/349

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