Joseph, J. and Gomathi, H. and Rao, G.P. (1997) Modification of carbon electrodes with zinc hexacyanoferrate. Journal of Electroanalytical Chemistry, 431 (002). pp. 231-235. ISSN 1572-6657
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Abstract
Electrodes modified with metal hexacyanoferrates find a unique place in the contemporary electrochemistry in view of their multifarious applications. The modification of carbon substrates with thin films of zinc hexacyanoferrate (ZnHCF) is reported for the first time. Stable surface modification is favored when the Zn=/Fe(CN)36- ratio is 1:1, while deviation from this ratio leads to interesting electrocrystallisation phenomena. K+ ion has a facile entry and exit into the lattice of ZnHCF compared to other cations such as Na+, Li+, NH4+ etc.
Item Type: | Article |
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Uncontrolled Keywords: | Modified electrodes; ZnHCF |
Subjects: | Electrodics and Electrocatalysis |
Divisions: | UNSPECIFIED |
Depositing User: | ttbdu cecri |
Date Deposited: | 20 Jul 2012 11:48 |
Last Modified: | 20 Jul 2012 11:48 |
URI: | http://cecri.csircentral.net/id/eprint/2845 |
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