Kulangiappar, K. and Anbukulandainathan, M. and Raju, T. (2010) Conversion of Benzylic Bromides to Benzaldehydes Using Sodium Nitrate As an Oxidant. Industrial Engineering & Chemical Research, 49. pp. 6670-6673.

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A simple and effective approach for the synthesis of benzaldehydes from benzylic bromides is reported using sodium nitrate as an oxidant with 10% sodium hydroxide. Benzyl bromide is oxidized to benzaldehyde in 91% yield with 98% conversion at 120 °C, whereas 82% of benzyl alcohol is obtained at a temperature of 80 °C in 80 min with 20% sodium nitrate solution.

Item Type: Article
Subjects: Electroorganic
Depositing User: ttbdar CECRI
Date Deposited: 18 Jan 2012 04:22
Last Modified: 18 Jan 2012 04:22
URI: http://cecri.csircentral.net/id/eprint/237

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