Palaniswamy, N. and Rajagopal, C. and Ravi, R. and Balakrishnan, K.
(1985)
Insitu study of metal surface by optical light reflection.
Bulletin of Electrochemistry , 01 (01).
ISSN 0256-1654
Abstract
Passive oxide films formed on metal surfaces can be broken by Veaddition of aggressive
ions like chloride while these films reinforced or prevented from being broken down by
the addition of inhibitors. This can be examined by monitoring the changes in the
reflectivity of the surface. The nature of the passive films formed has been studied by
optical reflection in NaCI-NaOH and NaCl-sodium benzoate media for a mild steel
electrode.
Likewise metal ions are used to reinforce corrosion inhibition or as inhibitors. Such
cations are thought of as being deposited as monolayers at potentials more positive than
the reversible Nernst potentials. The monolayer formationof lead on a mild steel surface
from solutions containmg ~ b + +ha s also been examined by monitoring the reflectance
changes
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