Jaya, S. and Prabhakarrao, G. and Prasadarao, T.
(1986)
Electrochemical phase formation on underpotential and overpotenial deposition of lead on glassy carbon.
Bulletin of Electrochemistry , 2 (1).
pp. 65-68.
ISSN 0256-1654
Abstract
The electrocrystaHisation of lead on GCE in underpotential and overpotential regions, is
described. The monolayer stripping peak occurring with large underpotential shift does not
correlate with the difference in chemical potential values of lead and carbon. The analysis of
the stripping peak revealed that the monolayer is formed by electrocrystallisation. The nature
of overpotential deposition is independent of the. presence or absence of UPD lead and is
dependent mainly on the concentration of lead in solution and on the nature of substrate.
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