Raju, T. and Kulangiappar, K. and Anbukulandainathan, M. and Muthukumaran, A. (2005) A simple and regioselective a-bromination of alkyl aromatic compounds by two-phase electrolysis. Tetrahedron Letters, 46 (41). pp. 7047-7050.
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Abstract
Electrochemical bromination of toluene and substituted toluenes by two-phase electrolysis yields the corresponding a-brominated products. The reaction has been carried out in a single compartment cell with platinum electrodes at 0 �C in chloroform using an aqueous sodium bromide solution (60%) containing a catalytic amount of HBr. Two-phase electrolysis results in high yields (60–95%) of monobromo compounds with very high regioselectivity (>95%).
| Item Type: | Article |
|---|---|
| Subjects: | Electroorganic |
| Divisions: | UNSPECIFIED |
| Depositing User: | TTBD CECRI |
| Date Deposited: | 17 Jan 2012 11:00 |
| Last Modified: | 18 Jan 2012 04:19 |
| URI: | http://cecri.csircentral.net/id/eprint/203 |
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