Raju, T. and Basha, C.A. (2005) Electrochemical cell design and development for mediated electrochemical oxidation-Ce(III)/Ce(IV)system. Chemical Engineering Journal, 114. pp. 55-65.

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Abstract

Electrochemically produced and regenerated cerium(IV) ions are a well-known redox mediator and used as a redox catalyst for the oxidation of alkyl aromatics. Detailed studies have been carried out on the design and the development of electrochemical cells for the electrochemical preparation of cerium(IV) methanesulphonate. In Ce(III)/Ce(IV) redox mediator system, cerium(IV) ion has been generated from cerium(III) in both divided and undivided electrochemical cell in high current efficiency and yield.

Item Type: Article
Uncontrolled Keywords: Electrochemical cell; Cerium(IV); Regeneration; Redox mediator; Undivided cell; Divided cell
Subjects: Electrohydrometallurgy
Pollution Control
Divisions: UNSPECIFIED
Depositing User: TTBD CECRI
Date Deposited: 13 Jan 2012 11:10
Last Modified: 13 Jan 2012 11:10
URI: http://cecri.csircentral.net/id/eprint/17

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