Ramprakash, Y. and Basu, S. and Bose, D.N.
(1988)
Anodic oxide and its effect on the performance of n-inp pec cells.
Bulletin of Electrochemistry , 04 (05).
pp. 497-504.
ISSN 0256-1654
Abstract
The effect of thin oxide films formed anodically on the surface of n-lnP was investigated in redox photoelectrochemical cells.
Studies relating to the I- V, C-V, spectral response and solar cell behaviour were carried out. In 0.1 M NaOH-0.1 M &Fe(CN)6,
4.1M K3Fe(CNlg, JO and n showed a decrease in their value for oxidized electrodes compared with bare InP. Barrier heights
derived from I-V and C-V data showed an increase with oxide. At A = 0.55 p m, the maximum value of the absolute quantum
efficiency was 0.68 without oxide; 0.55 and 0.40 respectively with increasing oxide thickness. In 1M NaOH-IM & Fe (CN)(
- 1M K3 Fe(CNI6, the PEC cell showed V, = 0.44 V, J, = 6.4 mAcm-2 , FF = 0.43 with oxide, at 66 mW ~mtun-gst~en.
halogen illumination
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