Joseph, J. and Barathi, S. and Gomathi, H. and Rao, G.P. (2002) Inorganic charge trapping interface containing prussian blue and copper hexacyanoferrate. Bulletin of Electrochemistry , 18 (6). pp. 267-271. ISSN 0256-1654

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Abstract

Ion exchange of Prussian Blue with transition metal ion leading to the formation of corresponding analogues is reported. Bilayers of Prussian Blue/CuHCF were constructed by a procedure involving the ion exchange of Fe2+ in Prussian Blue with Cu2+ leading to the formation of CuHCF overlayers. The bilayer thus formed shows interesting charge trapping characteristics due to restricted cation/electron movement through the film interface. UV-vis spectra and X-ray diffraction patterns give evidence for the bilayer formation and cyclic voltammetry is employed to show the effect of bilayers on electron/ion transfer

Item Type:	Article
Uncontrolled Keywords:	Ion exchange; Prussian Blue; X-ray diffraction
Subjects:	Electrodics and Electrocatalysis
Divisions:	UNSPECIFIED
Depositing User:	ttbdu cecri
Date Deposited:	27 Nov 2012 11:32
Last Modified:	27 Nov 2012 11:32
URI:	http://cecri.csircentral.net/id/eprint/1275

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