Suryanarayanan, V. and Ravisankar, R. and Noel, M.
(1999)
Comparison of electrooxidation of organic compounds in triethylamine - TRIS hydrogen fluoride in presence and absence of acetonitrile.
Bulletin of Electrochemistry, 15 (7-8).
pp. 289-292.
Abstract
Tbe electrochemical oxidation of ferrocene, quinhydrone and thioanisole on platinum, j,tla<;sy carhon and graphite electrodes were compared using cyclic voltammetry in RSN.3HF medium in the ahsence and presence of solvent CH3CN. All the three organic compounds show qualitatively similar responses on all the three electrodes as lon~ as their stahility is not affected by the medium. In general electron tnmsfer rate appears to be higher in neat E~N.3HF when compared to Et::\N.3HF/CII3CN system. Carbon electrodes aL<;o exhihit slight surface roughening in neat Et3N.3IIF medium.
| Item Type: |
Article
|
| Uncontrolled Keywords: |
Electrooxldatlon; organic compounds; cyclic voltammetry |
| Subjects: |
Electroorganic |
| Divisions: |
UNSPECIFIED |
| Depositing User: |
ttbdar CECRI
|
| Date Deposited: |
20 Feb 2012 06:09 |
| Last Modified: |
20 Feb 2012 06:09 |
| URI: |
http://cecri.csircentral.net/id/eprint/1165 |
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