Rajendran, S. and Mariajoany, R. and Apparao, B.V. and Palaniswamy, N.
(2000)
Synergistic Effect of Calcium Gluconate and Zn2+ on the Inhibition of Corrosion of Mild Steel in Neutral Aqueous Environment.
Transactions of the SAEST, 35.
3 & 4.
Abstract
As an alternative to the chromate containing corrosion inhibitors for mild steel in cooling water systems, the synergistic effect ofcalcium gluconate (CG) and Zn2+ on the inhibition ofcorrosion ofmild steel in neutral aqueous environment containing 60 ppm Cl-ion, a situation commonly encow1tered in cooling water systems, has beenevaluatedbytheweight-lossmethod. Theformulationconsisting of50ppm2n2' and200ppmCGhas 92% inhibition efficiency. A suitable mechanism ofcorrosion inhibition is proposed, based on the results obtained from the uv-visible absorption spectra and FTIR spectra. The protective film is found to be fluorescent and to consist ofFe2+-gluconate complex, Zn(OH)2 and Ca(OH)2'
Item Type: |
Article
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Uncontrolled Keywords: |
CorrOSIOn inhibition; calcium gluconate; fluorescence; surface analysis; synergism parameter |
Subjects: |
Electroorganic |
Divisions: |
UNSPECIFIED |
Depositing User: |
ttbdar CECRI
|
Date Deposited: |
21 Feb 2012 07:10 |
Last Modified: |
21 Feb 2012 07:10 |
URI: |
http://cecri.csircentral.net/id/eprint/1050 |
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